The recommended gasoline for most cars is regular 87 octane. One common misconception is that higher octane gasoline contains more cleaning additives than lower octane gas. All octane grades of all brands of gasoline contain engine cleaning detergent additives to protect against engine deposit build-up. In fact, using a gasoline with too high of an octane rating may cause damage to the emissions system.
Certain high performance engines benefit from use of high octane fuel. For other engines, using a fuel with a higher octane rating than the vehicle requires sends unburned fuel into the emissions system and catalytic converter. This puts unecessary stress on the emissions system. For some vehicles, a rotten egg smell coming from the tailpipe signals use of too-high octane gas
Octane rating of a spark ignition engine fuel is the detonation resistance (anti-knock rating) compared to a mixture of iso-octane (2,2,4-trimethylpentane, an isomer of octane) and n-heptane. By definition, iso-octane is assigned an octane rating of 100, and heptane is assigned an octane rating of zero. An 87-octane gasoline, for example, possesses the same anti-knock rating of a mixture of 87% (by volume) iso-octane, and 13% (by volume) n-heptane. This does not mean, however, that the gasoline actually contains these hydrocarbons in these actual proportions. It simply means that it has the same detonation resistance properties as the described 'standard' defined mixture.
